Of course, I forgot that R20 will lift the pin 6 pad to +32V when the U3 is removed and is not holding it down. Before, pin 6 voltage was higher than it should have been but it was later found to be caused by the missing negative voltage on pin 4.
Your U3 pin 2 voltage problem was fixed somehow by removing U3.
Before, the D7 diodes were backwards causing the negative supply to be -3.9V then you corrected their polarity and measured the correct -1.5V. But now on U3 pin 4 pad you measure only +0.3 or -0.3V?? What changed, a broken trace on the pcb??