my experiences:
60/40 SnPb (Tin/Lead) solder: good for soldering electronics.
SnAg (Tin/Silver) solder: works if one doesn't have anything else, hassle to use, doesn't wet well, kind of makes a mess. I have a few boards mostly soldered using this stuff.
in general though, I much prefer 60/40 Sn/Pb for soldering circuit boards and similar.
for a while, I was using a 45W iron, which was pretty good... but then it broke (mostly stopped getting hot...).
I had been using another 25W iron, but this is more annoying. it takes a long time to get hot and solder things, and touching anything "heavy" (such as thick wire) can cause it to lose temperature and get stuck (as the solder solidifies).
I have a newer/nicer 35W iron, but I have it in my bag and mostly use it when off places and a need arises to solder something (also duct tape, a glue gun, ... can be pretty useful as well).
all my irons are fixed rating.
I had used soldering stations before (elsewhere), but for a lot of this stuff, had been doing quick/dirty stuff like sticking things together or tinning wires, so had used them at full power (IIRC, 80W or something). but, even something like this has a hard-time reasonably quickly tinning an 8AWG or 10AWG wire, so one ends up essentially mostly tinning parts of the wire at a time, and dealing with the issue that heat likes traveling a fair distance down such a wire (like, try to tin an 8AWG and a good several feet or so of the wire gets hot, *...), but not nearly so readily across the wire (one trick is to try to twist it tight and tin a ring around the wire, which makes heat flow better to the rest of it, making the rest a little easier to tin).
this is mostly because IME, when tinning wires, it seems best if it gets really hot really fast, so that the solder flows right on. but, sadly, this isn't really doable with thick wires.
*: these were basically the power wires for brushed DC motors roughly about the size of 1lb coffee cans.
they were being tinned mostly as this made them work a bit better with the type of clamp-down terminals being used.