pootler,
1. Are you using a Schottky diode?
2. The ammeter can add significant resistance. Try repeating the test without the ammeter, just monitor the voltage.
3. Make sure you have good solid connections.
a) Your video shows an immediate voltage drop from 5v to 4.15v. That suggests a standard silicon diode (not Schottky) and/or relatively high ammeter resistance. Even 1 ohm resistance is too high for this low-headroom circuit.
b) I am further troubled by the additional drop to 3.24v in roughly 3 seconds. That sounds like the caps are not really a total of 8 farads, more like under 3 farads.
Let us know what happens.
Frank
O.K
Shottky - Yes - see pic
2 x 5.5V 4 farad supercaps wired in parallel - yes - see pic You can ( just about) see the 5.5V 4 F on the side of the cap.
I do have a feeling that the voltage drop is less sudden if multimeter is not in circuit for reading current, however it still wouldn't explain the fact is doesn't work in the car?
If its important, i will do a vid of just voltage.
Many Thanks
pootler