What is the best temp for a soldering iron tip ?
It's not that simple.
You care about the temperature of the joint.
With today's tiny components, you typically end up with
a tiny tip with small heat capacity trying to raise the temperature
of a larger area. The ground plane end of a cap is typically
much harder to solder than the free end.
Cheap irons attack the problem by raising the tip temperature
so you can melt the solder with the heat capacity available in the tip.
Weller irons have the temperature control mechanism right at the tip,
so it can turn up power relatively quickly.
Irons like the Metcal use RF and get VERY tight coupling between power
input and temperature. First time I used a Metcal, I was amazed at how
quickly a lower temperature tip could melt the joint.
How does a tip stay "tinned" with lead free solder ?
Plated tips don't stay "tinned" with lead solder either.