Fred Abse said:
Switching capacitors from series to parallel does not change each individual C,
hence, neglecting switching losses, both charge and energy remain the
same. I assume that is what you mean by a flying capacitor converter.
What I meant was charging a cap with another cap. Without tricky quasi-resonant or inverter circuits, you inevitably have to do this (under the presumption that a constant DC output is desired), and this inevitably leads to loss. But the 50% loss only occurs to the *change* in energy, so if you make this change an arbitrarily small fraction of the supply voltage, efficiency can be quite high. Hence why things like MAX232 can be ~95% efficient despite pumping caps into caps.
When you mentioned a mechanical method, I envisioned a stack of capacitors charged by the high-voltage source, then a rotor to ferry a bit of charge at a time from the stack to a reservoir. The rotor would be equipped with capacitors, and contacts would be present on each side, so that the rotor is charged by the HV stack on one side, then connected in parallel on the other side to deliver its charge. The rotor has to be big enough, and insulating, so that arc-over doesn't occur at either end of the rotor. The capacitors on the rotor have to be big enough to deliver a useful amount of charge, enough times per second, to meet the design current and efficiency specs.
Of course, no standing capacitor chain need be provided; the rotor can simply mesh with series-connected contacts, providing all the capacitance itself. Likewise, two or more rotors could be used, in make-before-break mode, to eliminate the DC link capacitor. YMMV; a standing cap bank would be wise for lightning collection, but unnecessary for experiments (in either direction, step-up or step-down). Three rotors in make-before-break would be quite suitable for supplying a conventional (inductor based) converter, transforming, say, 1-10kV into 1.5V or 12V or 160V, etc.
OTOH, when a capacitance is changed, work is performed. An electrophorus works by applying force to seperate charges, increasing the voltage. If capacitance falls linearly, voltage rises linearly, but energy rises as voltage squared, so the energy rises linearly. The difference comes from the work input, which by hand, feels negligible against a 100g electrophorus. This might be confusing to perpetual motion types, who are fond of electric or magnetic devices with forces so weak, they seem to move of their own accord.
Tim