Hey Y2KEDDIE !
IMHO Toner Transfer is a PITA ... many, many people have managed to get decent results using this method .... the common denominator appears to be meticulous attention to detail following a relatively lengthy trial and error period. Perhaps the biggest problem is the large number of variables that are simply impossible to quantify ... things like printer type, toner type, printer fusion temperature, paper moisture content, toner moisture content, transfer temperature, and the list goes on and on ....
Even assuming the toner transfer process goes perfectly, the learning curve on etching & drilling can take several attempts to get right.
What are the alternatives? Obviously if the design is headed toward production then having the prototype PCBs made by a PCB mfg is truly the best option. If the PCB is a one-off DIY project it can be harder to justify the cost of paying for a professionally made PCB ... and with a one-off DIY project the out-of-pocket costs are paramount to the "hobby time wasted" on the project.
My answer is to "cut" prototype PCBs on a CNC router. With my current machine I can maintain 10mil traces with 10mil spacing which generally meets my needs ... but the process can be time consuming. For a simple PCB I typically create the primitives directly in a CAD/CAM program designed for creating gCode files ... more complex PCBs I create in Altium Designer then export the GERBER files and then import them into my CNC CAD/CAM software ... and then make requisite modifications to generate suitable gCode files ... For two sided PCBs I create two "single-sided" PCBs from 0.030" thick PCB material and simply glue them together ... it is easier for me than flipping a two sided PCB over and indexing it properly.
Other methods include:
Painting the copper with black paint and then using a CNC Laser to ablate the paint ... there is a lengthy thread on that method elsewhere in this forum.
Modifying a laser printer to direct print onto a PCB. I don't know that anyone has ever successfully achieved this method, but I have read many "starts" to said project. I have some flexible 0.007" thick PCB material that **in theory** will feed directly into my HP LaserJet ... but I have never tried it.
Modifying an inkjet printer to direct print resist to PCBs. There is a very detailed "how to" for a particular model inkjet printer floating around on the net, but the modifications are for a printer that hasn't been in production since the early 2000s ... I searched ebay and other sources for one of these printers for a very long time and never found one ...
The most promising technology I have read about involves "conductive inks". In theory almost any 3D printer with a specially designed print-head could "print" traces onto any suitable substrate ... with a 0.1mm nozzle the nominal trace width would be ~4mil which should translate safely to ~6mil trace + 6mil spacing ... The biggest problem with this technology right now is that the inks & print heads simply aren't readily available to hobbyist.
At the end of the day, making one PCB is expensive and time consuming no matter how you do it ... it is all about finding the method least offensive to you
Fish