You trigger the 'scope on one channel with one of your digital signals and apply the other digital signal to the other channel. When you select add mode, you will see a stable waveform (triggered sweep) from the first channel with the second channel superimposed on it. If the second channel is synchronous with the first channel, you will be able to see any differences in timing, such as a delay from when the first channel is triggered and the rising (or falling) edge of the signal on the second channel.