The value of LED lighting would be that they use much less power than other types of lighting. That means you'd have brighter lights for a longer period of time at night. The first thing I would do, is check if any of the solar powered garden light products you can find have LED lighting, ...my guess would be probably. Then decide if the assemblies the garden light system supply, can be adapted for your planter configuration. If you're already planning a solar powered pump (I assume with a rechargeable battery system, so it'll run at night), then you'll already have your power system for your LED lights (if you just want to add those LED's to the pump power system). It'll be up to you whether you think you need a second solar powered rechargable battery system for your LED lights.
Just giving you ideas for possibilities to consider.
If you've got a recharging battery system for your solar powered pump, you decide if you want the pump AND the LEDs to run at night, or just the LED's (the pump will use a lot more power from your battery, than the LED's alone would).
I know you said you plan to run waterfall at night, just giving you something to think about.
Considering the fact that LED's consume considerably less power, I'd be thinking about just adding the LED's to the power from your solar powered pump system, and skipping the garden light system altogether, ...but the trade-off is, that if you had the garden-light solar recharging system, you'd have more power (for longer duration run-time at night).
The practical consideration here, it seems to me, is that the pump will require considerable power to run off a rechargable battery, and I would guess you'd only get a few hours of pump run-time from it, after the sun goes down. (It'd take a heck of a battery system, to keep a water pump running all night long).
Hope the above offers some help in your planning.