Do you want to change 3.3V to 240V AC, or do you want to control 240V AC with a 3.3V signal?
If it's the latter, use the 3.3V to switch on a transistor, and use the transistor to switch on a relay. Using a solid-state relay is an alternative, especially if If you can't find a 3.3V relay. Make sure it's rated for 240V and can handle the necessary current.